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Thermodynamic study of lead ion removal by adsorption onto nanographene sheets | ||
Journal of Physical & Theoretical Chemistry | ||
مقاله 7، دوره 10، شماره 1، تیر 2013، صفحه 59-67 اصل مقاله (425.26 K) | ||
نوع مقاله: Research Paper | ||
نویسندگان | ||
Y. Saghapour* ؛ M. Aghaie* ؛ K. Zare* | ||
- | ||
چکیده | ||
A batch adsorption study was applied to investigate the adsorption of Pb2+ ions from aqueous solution by nanographene (nG).The adsorption percentage of Pb2+ions onto nG samples at different initial pH, contact time (tc), adsorbent dosage (mnG) and temperature (T) were investigated. The results showed that nG is an excellent adsorbent for Pb2+ions removal from aqueous solutions with an adsorption percentage of up to 79.8% at initial Pb2+concentration of 20ppm and temperature of 298K.The experimental data could be well described by the Freundlich and Langmuire isotherm model; thermodynamic parameters of adsorption process (AG0, AH0, ASo) were also evaluated. The overall adsorption process was exothermic and spontaneous in nature .The results indicate that Pb2+ions adsorption onto nG may be chemisorption. | ||
کلیدواژهها | ||
Nanographene؛ Pb2+ions؛ Adsorption؛ Isotherm؛ thermodynamics | ||
آمار تعداد مشاهده مقاله: 861 تعداد دریافت فایل اصل مقاله: 613 |