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In-situ synthesis and characterization of conducting metal — polyaniline nanocomposites | ||
Journal of Physical & Theoretical Chemistry | ||
مقاله 3، دوره 5، شماره 4، اردیبهشت 2009، صفحه 13-18 اصل مقاله (158.32 K) | ||
نوع مقاله: Research Paper | ||
نویسندگان | ||
M. Yari* ؛ S. Sedaghat* | ||
- | ||
چکیده | ||
Metal—Polyaniline nanocomposites such as Platinum-Polyaniline nanocomposite is prepared by in situ oxidative polymerization of aniline and reduction of Pt+4 ions into Pt nanoparticles. The polymerization of aniline was carried out in the presence of 1(2PtCN6 [Potassium Hexa Cyano Platinate (IV)] as oxidizing agent. During the reaction aniline monomers undergo oxidation and form polyaniline (PANT) whereas the reduction of [PtCN6]-2 ions result the formation of Pt nanoparticles. Nano-sized Pt particles were prepared by controlled reduction of Platinum precursor in micro emulsion medium, stabilized with the anionic surfactant (AOT). Micro emulsion solution acts as both emulsifier and dopant to obtain stable nanocomposite. PANI-AOT-Pt nanocomposite is characterized by FT-IR spectroscopy and scanning microelectronic microscopy (SEM). | ||
کلیدواژهها | ||
Polyaniline؛ Nanocomposite؛ Pt Nanoparticles | ||
آمار تعداد مشاهده مقاله: 682 تعداد دریافت فایل اصل مقاله: 613 |