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Kinetic and thermodynamic studies of adsorption of 4-chloro-2-nitrophenol on nano- Ti02 | ||
Journal of Physical & Theoretical Chemistry | ||
مقاله 5، دوره 8، شماره 1، مرداد 2011، صفحه 33-38 اصل مقاله (104.67 K) | ||
نوع مقاله: Research Paper | ||
نویسندگان | ||
A. Mehrizad* ؛ K. Zare* ؛ H. Dashti Khavidaki* ؛ S. Dastmalchi* ؛ H. Aghaie* ؛ P. Gharbani* | ||
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چکیده | ||
Adsorption capacity of 4-chloro-2-nitrophenol (4C2NP) onto nano-Ti02 from aqueous solutions was investigated in a batch system by considering the effects of various parameters like contact time, nano- TiO2 dosage, initial pH and initial 4C2NP concentration. Optimum conditions for 4C2NP adsorption were found to be initial pH z 2, nano-TiO2 closer- 0.01 g and equilibrium time 1 h. The adsorption kinetic data were analyzed using pseudo-first and pseudo-second order models. It was found that the pseudo-second-order kinetic model was the most appropriate model, describing the adsorption kinetics. The thermodynamic parameters such as AG°, MP and AS° were computed from the experimental data. These values show that the adsorption of 4C2NP onto nano-Ti02 is spontaneous and endothermic. | ||
کلیدواژهها | ||
Adsorption؛ Kinetic؛ Thermodynamic؛ 4-Chloro-2-nitrophenol؛ Nano-TiO2 | ||
آمار تعداد مشاهده مقاله: 659 تعداد دریافت فایل اصل مقاله: 334 |